Chemistry, like all the natural sciences, begins with the direct observation of nature¡ª in this case, of matter.41459-42-1, Name is 3-Bromo-2-(bromomethyl)propanoic acid, SMILES is O=C(O)C(CBr)CBr, belongs to bromides-buliding-blocks compound. In a document, author is Budweg, Svenja, introduce the new discover, Name: 3-Bromo-2-(bromomethyl)propanoic acid.
Transfer-dehydrogenation of secondary alcohols catalyzed by manganese NNN-pincer complexes
Novel catalytic systems based on pentacarbonylmanganese bromide and stable NNN-pincer ligands are presented for the transfer-dehydrogenation of secondary alcohols to give the corresponding ketones in good to excellent isolated yields. Best results are obtained using di-picolylamine derivatives as ligands and acetone as an inexpensive hydrogen acceptor. Besides high activity for benzylic substrates, aliphatic alcohols, as well as steroid derivatives, are readily oxidized in the presence of the optimal phosphorus-free catalyst.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 41459-42-1 is helpful to your research. Name: 3-Bromo-2-(bromomethyl)propanoic acid.