The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 2746-25-0, Name is 1-(Bromomethyl)-4-methoxybenzene, SMILES is COC1=CC=C(CBr)C=C1, in an article , author is Rocha, Mariana, once mentioned of 2746-25-0, Name: 1-(Bromomethyl)-4-methoxybenzene.
Diethylaminophenyl-based Schiff base Cu(II) and V(IV) complexes: experimental and theoretical studies and cytotoxicity assays
An N,N,O,O donor Schiff base blocking ligand [H2L = 6,6′-((1E,1’E)-(ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))bis(3-(diethylamino)phenol), 1] has been used to synthesize mononuclear [CuL]center dot H2O (2) and [VO(L)] (3) complexes. The ligand and complexes have been characterized by elemental, spectral (FTIR and UV-vis) and thermogravimetric analysis. The molecular structures of 1 and 2 have been confirmed by single crystal X-ray diffraction studies. The crystal structure of the ligand (1) indicates that the molecule is sited on a crystallographic inversion centre and the planar conformation of the salicylideneimine moiety is favored by two intramolecular O-HN center dot center dot center dot 1 hydrogen bonds forming S(6) ring motifs. The copper(ii) center in complex 2 is coordinated in a square planar fashion. The presence of an extended pi-system in the complex (two chelate rings and two phenyl rings) facilitates the formation of chelate ring (CR)center dot center dot center dot pi non-covalent interactions. DFT calculations have been performed to explore the energetic features of unconventional CR center dot center dot center dot pi and hydrogen bonding interactions that are observed and described in the solid state of 2. Moreover, we have studied how the energy of the CR center dot center dot center dot pi interaction is influenced by the substituent of the phenyl ring. In addition, the cytotoxic effect of the compounds has been tested against MG-63 (human osteosarcoma), HT-29 (human colorectal) and MCF7 (breast) cancer cell lines using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay.
Interested yet? Read on for other articles about 2746-25-0, you can contact me at any time and look forward to more communication. Name: 1-(Bromomethyl)-4-methoxybenzene.