Adachi, Yohei; Arai, Fuka; Yamada, Kohei; Kurihara, Maho; Ohshita, Joji published the artcile< Optical Properties of Boron-Incorporated Analogues of Tetrathienoanthracene>, Related Products of 576-83-0, the main research area is borepin incorporated analog tetrathienoanthracene preparation emission fluorescence DFT; crystal structure borepin incorporated analog tetrathienoanthracene; mol structure borepin incorporated analog tetrathienoanthracene.
B-introduced aromatic systems have caught the interest of materials chemists because of their unique photophys. properties and tunable Lewis acidity. The authors prepared B-incorporated analogs of tetrathienoanthracene (TTA) containing aromatic borepin rings. Despite the low aromaticity of the borepin rings, the bis-borepins showed high chem. stability and no decomposition in air. The bis-borepins exhibited bluish fluorescence at room temperature and bright greenish phosphorescence at a low temperature The specific electronic structure of the B-incorporated analogs of TTA was revealed by comparing the photophys. properties of the bis-borepins with those of TTA and the parent mono-borepin. The electronic structure was further studied by DFT/TD-DFT calculations Titration experiments using cyanide as the anion revealed the high Lewis acidity and the turn-off fluorescence response of the bis-borepins to the addition of cyanide.
Organometallics published new progress about Anthracenes Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), SPN (Synthetic Preparation), PROC (Process), PREP (Preparation) (borepin-incorporated analogs of tetrathienoanthracene). 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Related Products of 576-83-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary