Miyake, Yoshihiro; Nakajima, Kazunari; Nishibayashi, Yoshiaki published the artcile< Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts>, COA of Formula: C10H11BrO2, the main research area is oxidative decarboxylation arylacetic acid photoredox catalyst; benzyl radical formation radical addition electron deficient alkene.
Reactions of alkenes with arylacetic acids bearing an amino group at the para-position in the benzene ring in the presence of a catalytic amount of transition metal polypyridyl complexes as photocatalysts under visible light illumination proceed smoothly to give the corresponding benzylated products via oxidative decarboxylation in good to high yields. E.g., in presence of [Ir(ppy)2(bpy)]BF4 as catalyst, visible light-mediated oxidative decarboxylation of 4-Me2NC6H4CH2CO2H in presence of (E)-PhCH:C(CN)CO2Et gave 85% 4-Me2NC6H4CH2CHPhCH(CN)CO2Et.
Chemical Communications (Cambridge, United Kingdom) published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 14062-30-7 belongs to class bromides-buliding-blocks, and the molecular formula is C10H11BrO2, COA of Formula: C10H11BrO2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary