Yang, Jin; Sun, Bin; Ding, Hao; Huang, Pan-Yi; Tang, Xiao-Li; Shi, Rong-Cheng; Yan, Zhi-Yang; Yu, Chuan-Ming; Jin, Can published the artcile< Photo-triggered self-catalyzed fluoroalkylation/cyclization of unactivated alkenes: synthesis of quinazolinones containing the CF2R group>, Computed Properties of 20776-50-5, the main research area is alkenyl quinazolinone fluoroalkyl bromide tandem photochem fluoroalkylation radical cyclization; fluoroalkyl fused quinazolinone preparation green chem.
A novel photo-triggered self-catalyzed fluoroalkylation/cyclization of quinazolinones containing unactivated alkenes with various fluoroalkyl bromides was developed. This transformation exhibited excellent substrate generality with respect to both the coupling partners. This was the first example describing the Csp3-Br bond homolysis of alkyl bromides via a substrate (quinazolinones) induced energy transfer process. Addnl., the mild conditions, tolerance to a wide range of functional groups and operational simplicity make this protocol practical for the synthesis of fluorine-containing ring-fused quinazolinones.
Green Chemistry published new progress about Acetamides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 20776-50-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H6BrNO2, Computed Properties of 20776-50-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary