Budiman, Yudha P.; Friedrich, Alexandra; Radius, Udo; Marder, Todd B. published the artcile< Copper-Catalysed Suzuki-Miyaura Cross-Coupling of Highly Fluorinated Aryl Boronate Esters with Aryl Iodides and Bromides and Fluoroarene-Arene π-Stacking Interactions in the Products>, Quality Control of 576-83-0, the main research area is fluorophenylboronic acid pinacol ester haloarene copper catalyst Suzuki coupling; biaryl preparation.
A combination of copper iodide and phenanthroline as the ligand is an efficient catalyst for Suzuki-Miyaura cross-coupling of highly fluorinated boronate esters (aryl-Bpin) with aryl iodides and bromides to generate fluorinated biaryls in good to excellent yields. This method represents a nice alternative to traditional cross-coupling methods which require palladium catalysts and stoichiometric amounts of silver oxide. The investigation revelaed that π···π stacking interactions dominated the mol. packing in the partly fluorinated biaryl crystals. They were present either between the arene and perfluoroarene, or solely between arenes or perfluoroarenes, resp.
ChemCatChem published new progress about Aryl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Quality Control of 576-83-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary