Hu, Deqing; Jiang, Xuefeng published the artcile< Stepwise benzylic oxygenation via uranyl-photocatalysis>, Recommanded Product: 1-Bromo-3-ethylbenzene, the main research area is carboxylic acid ketone alc preparation photochem; benzylic mol stepwise oxygenation uranyl catalyst.
Stepwise oxygenation at the benzylic position (1°, 2°, 3°) of aromatic mols. was comprehensively established under ambient conditions via uranyl photocatalysis to produce carboxylic acids, ketones, and alcs., resp. The accuracy of the stepwise oxygenation was ensured by the tunability of catalytic activity in uranyl photocatalysis, which was adjusted by solvents and additives demonstrated through Stern-Volmer anal. Hydrogen atom transfer between the benzylic position and the uranyl catalyst facilitated oxygenation, further confirmed by kinetic studies. Considerably improved efficiency of flow operation demonstrated the potential for industrial synthetic application.
Green Chemistry published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 2725-82-8 belongs to class bromides-buliding-blocks, and the molecular formula is C8H9Br, Recommanded Product: 1-Bromo-3-ethylbenzene.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary