Jin, Cong-Yang; Du, Ji-Yuan; Zeng, Chao; Zhao, Xian-He; Cao, Ye-Xing; Zhang, Xiang-Zhi; Lu, Xin-Yun; Fan, Chun-An published the artcile< Hypervalent iodine(III)-mediated oxidative dearomatizing cyclization of arylamines>, Application In Synthesis of 16426-64-5, the main research area is amido aryl amine iodane mediated oxidative dearomatizing spirocyclization; spiro lactam cyclohexadiene iminium preparation.
An oxidative dearomatizing cyclization of aryl amines promoted by iodobenzene bis(trifluoroacetate) [PhI(CF3CO2)2] was explored, leading to a novel synthetic approach to functionalized spirocyclic building blocks containing a structurally unique dieniminium moiety. This unprecedented methodol., featuring oxidative dearomatization and carbon-carbon bond-forming cyclization, to some extent, not only expands the synthetic potential of hypervalent iodine chem., but also enriches the oxidation chem. of arylamines.
Advanced Synthesis & Catalysis published new progress about Aromatic amides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 16426-64-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrNO4, Application In Synthesis of 16426-64-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary