Jinno, Shunki; Senoo, Takahiro; Mori, Keiji published the artcile< Access to ortho-Hydroxyphenyl Ketimines via Imine Anion-Mediated Smiles Rearrangement>, Computed Properties of 576-83-0, the main research area is phenoxy benzonitrile aryl bromide nucleophilic addition Smiles rearrangement; phenyliminomethyl aryl phenol preparation.
Access to N-(2-halophenyl)-2-hydroxyphenylimine derivatives via imine anion-mediated Smiles rearrangement. When 2-(2-halophenoxy)benzonitriles were treated with 1.2-1.4 equiv of organolithium reagents, nucleophilic addition to the nitrile group followed by Smiles rearrangement occurred to give various N-(2-halophenyl)-2-hydroxyphenylimine derivatives, which are sometimes difficult to synthesize by the conventional acid-promoted condensation reaction between carbonyl compounds and aniline derivatives, in good to excellent chem. yields (up to 91%).
Organic Letters published new progress about Aromatic ethers Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Computed Properties of 576-83-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary