Moon, Patrick J.; Fahandej-Sadi, Anis; Qian, Wenyu; Lundgren, Rylan J. published the artcile< Decarboxylative Benzylation of Aryl and Alkenyl Boronic Esters>, Application of C10H11BrO2, the main research area is aryl boronic ester arylacetate potassium copper decarboxylative benzylation catalyst; alkenyl boronic ester arylacetate potassium copper decarboxylative benzylation catalyst; copper arylacetate aryl boronic ester potassium acetate decarboxylative benzylation; diarylmethane preparation; aerobic catalysis; boron; copper; cross-coupling; decarboxylation.
The copper-catalyzed decarboxylative benzylation of aryl and alkenyl boronic esters with electron-deficient aryl acetates is reported. The oxidative coupling proceeds under mild, aerobic conditions and tolerates a host of potentially reactive electrophilic functional groups that would be problematic with traditional benzylation methods (aryl iodides and bromides, protic heteroatoms, aldehydes, Michael acceptors). A reaction pathway in which a benzylic nucleophile is generated by aryl acetate decarboxylation and in turn is intercepted by the catalyst to form diarylmethane products is supported by mechanistic studies.
Angewandte Chemie, International Edition published new progress about Alkanes Role: SPN (Synthetic Preparation), PREP (Preparation) (diarylmethane). 14062-30-7 belongs to class bromides-buliding-blocks, and the molecular formula is C10H11BrO2, Application of C10H11BrO2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary