Schumann, Andre; Reiss, Fabian; Jiao, Haijun; Rabeah, Jabor; Siewert, Jan-Erik; Krummenacher, Ivo; Braunschweig, Holger; Hering-Junghans, Christian published the artcile< A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation>, Electric Literature of 576-83-0, the main research area is aryl triphosphirane titanocene fragmentation preparation reactivity mechanism; crystal structure mol optimized triphosphirane titanocene diphosphene preparation.
Triphosphiranes are three-membered phosphorus cycles and their fundamental reactivity has been studied in recent decades. We recently developed a high-yielding, selective synthesis for various aryl-substituted triphosphiranes. Variation of the reaction conditions in combination with theor. studies helped to rationalize the formation of these homoleptic phosphorus ring systems and highly reactive intermediates could be isolated. In addition we showed that a titanocene synthon [Cp2Ti(btmsa)] facilitates the selective conversion of these triphosphiranes into titanocene diphosphene complexes. This unexpected reactivity mode was further studied theor. and exptl. evidence is presented for the proposed reaction mechanism.
Chemical Science published new progress about Crystal structure. 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Electric Literature of 576-83-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary