Tahir, Norini; Muniz-Miranda, Francesco; Everaert, Jonas; Tack, Pieter; Heugebaert, Thomas; Leus, Karen; Vincze, Laszlo; Stevens, Christian V.; Van Speybroeck, Veronique; Van Der Voort, Pascal published the artcile< Immobilization of Ir(I) complex on covalent triazine frameworks for C-H borylation reactions: A combined experimental and computational study>, Recommanded Product: 3-Bromobenzotrifluoride, the main research area is covalent triazine framework preparation carbon hydrogen borylation computational exptl.
Metal-modified covalent triazine frameworks (CTFs) have attracted considerable attention in heterogeneous catalysis due to their strong nitrogen-metal interactions exhibiting superior activity, stability and hence recyclability. Herein, authors report on a post-metalation of a bipyridine-based CTFs with an Ir(I) complex for C-H borylation of aromatic compounds Phys. characterization of the Ir(I)-based bipyCTF catalyst in combination with d. functional theory (DFT) calculations exhibit a high stabilization energy of the Ir-bipy moiety in the frameworks in the presence of B2Pin2. By using B2Pin2 as a boron source, Ir(I)@bipyCTF efficiently catalyzed the C-H borylation of various aromatic compounds with excellent activity and good recyclability. In addition, XAS anal. of the Ir(I)@bipyCTF gave clear evidence for the coordination environment of the Ir.
Journal of Catalysis published new progress about Borylation. 401-78-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3, Recommanded Product: 3-Bromobenzotrifluoride.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary