China, Hideyasu’s team published research in Molecules in 2021 | 20776-50-5

Molecules published new progress about Acetylation. 20776-50-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H6BrNO2, COA of Formula: C7H6BrNO2.

China, Hideyasu; Kageyama, Nami; Yatabe, Hotaka; Takenaga, Naoko; Dohi, Toshifumi published the artcile< Practical synthesis of 2-iodosobenzoic acid (IBA) without contamination by hazardous 2-iodoxybenzoic acid (IBX) under mild conditions>, COA of Formula: C7H6BrNO2, the main research area is cyclic organoiodine compound iodosobenzoic acid preparation solvolytic functionalization; Oxone®; cyclic organoiodine(III) compounds; water, solvolytic functionalization, mild condition, metal-free, 2-iodosobenzoic acid.

A convenient and practical method for the preparation of nonexplosive cyclic hypervalent iodine(III) oxidants as efficient organocatalysts and reagents for various reactions using oxone in aqueous solution under mild conditions at room temperature is reported. The thus obtained 2-iodosobenzoic acids (IBAs) could be used as precursors of other cyclic organoiodine(III) derivatives by the solvolytic derivatization of the hydroxy group under mild conditions of 80° or lower temperature These sequential procedures are highly reliable to selectively afford cyclic hypervalent iodine compounds in excellent yields without contamination by hazardous pentavalent iodine(III) compound

Molecules published new progress about Acetylation. 20776-50-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H6BrNO2, COA of Formula: C7H6BrNO2.

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary