Cui, Penglei; Li, Sida; Wang, Xianjin; Li, Ming; Wang, Chun; Wu, Lipeng published the artcile< Visible-Light-Promoted Unsymmetrical Phosphine Synthesis from Benzylamines>, SDS of cas: 3959-07-7, the main research area is photochem deaminative alkylation reaction benzylamine Katritzky salt phenylphosphine; unsym tertiary phosphine preparation electrochem fluorescence.
Herein, by applying visible-light photoredox catalysis, the authors have achieved the catalytic deaminative alkylation of diphenylphosphine and Ph phosphine with benzylamine-derived Katritzky salts at room temperature The use of Eosin Y as photoredox catalyst and visible light can largely promote the reaction. Unsym. tertiary phosphines were successfully synthesized, including phosphines with three different substituents that are otherwise difficult to obtain.
Organic Letters published new progress about Alkylation (photochem. deaminative alkylation reaction). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, SDS of cas: 3959-07-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary