Kashida, Junki; Shoji, Yoshiaki; Fukushima, Takanori published the artcile< Synthesis and Reactivity of Cyclic Borane-Amidine Conjugated Molecules Formed by Direct 1,2-Carboboration of Carbodiimides with 9-Borafluorenes>, Related Products of 576-83-0, the main research area is cyclic borane amidine conjugated preparation carboboration carbodiimide borafluorene; crystal mol structure cyclic borane amidine conjugate; amidines; borafluorenes; carboboration; carbodiimides; heterocycles.
Efficient 1,2-carboboration reactions to the C:N bond of carbodiimides with 9-borafluorenes, which give rise to cyclic borane-amidine conjugates with a seven-membered BNC5 ring, are reported. The resulting cyclic borane-amidine conjugates can be hydrolyzed into an acyclic bifunctional biaryl compound carrying both boronic acid and amidine groups, rendering the utility of the two-step protocol for the synthesis of multi-functionalized mol. systems with a potential as a supramol. building block. Furthermore, the conjugated structure of the cyclic boron-amidine compounds can be changed upon alkylation of the boron atom that increases the coordination number of boron. The combination of Lewis acid (borane) and conjugated base (amidine) provides rich structural diversity of heteroatom-containing π-conjugated systems.
Chemistry – An Asian Journal published new progress about Borylation (carboboration). 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Related Products of 576-83-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary