Yeung, Jason; Becker, Matthias; Stephan, Douglas W. published the artcile< Towards macrocyclic frustrated Lewis pairs>, Safety of 2,4,6-Trimethylbromobenzene, the main research area is crystal structure mol boron macrocycle frustrated Lewis pair preparation; macrocyclic frustrated Lewis pair boron nitrogen bond macrocycle preparation.
Macrocycles with and without B-N bonds were prepared from reaction of C6F5BH2·SMe2 or MesBH2 with the 2,6-pyridinedimethanol derivatives Both classes of macrocycle reacted with B(C6F5)3 but were unreactive to small mols. These observations provide insights for the subsequent design of macrocyclic FLPs for multi-electron reactions.
Dalton Transactions published new progress about B-N bond. 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Safety of 2,4,6-Trimethylbromobenzene.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary