Dan, Demin; Chen, Fubo; Zhao, Whenshu; Yu, Han; Han, Sheng; Wei, Yongge published the artcile< Chromium-catalysed efficient N-formylation of amines with a recyclable polyoxometalate-supported green catalyst>, Related Products of 3959-07-7, the main research area is formamide preparation; formic acid amine chromium catalyst formylation green chem; polyoxometalate based chromium catalyst preparation crystallinity.
A simple and efficient protocol for the formylation of amines with formic acid, catalyzed by a polyoxometalate-based chromium catalyst was described. Notably, this method showed excellent activity and chemoselectivity for the formylation of primary amines, diamines were successfully employed. Importantly, the chromium catalyst is potentially non-toxic, environmentally benign and safer than the widely used high valence chromium catalysts such as CrO3 and K2Cr2O7. The catalyst can be recycled several times with a negligible impact on activity. Finally, a plausible mechanism was provided based on the observation of intermediate and control experiments
Dalton Transactions published new progress about Amines Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Related Products of 3959-07-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary