Product Details of 13465-09-3In 2020 ,《Synthesis, properties and structures of gallium(III) and indium(III) halide complexes with neutral pnictine coordination》 appeared in Journal of Organometallic Chemistry. The author of the article were Cairns, Kelsey R.; Greenacre, Victoria K.; Grose, Laura A.; Levason, William; Reid, Gillian; Robinson, Fred. The article conveys some information:
A series of Group 13 halide complexes of SbnBu3, [GaX3(SbnBu3)] and [InX3(SbnBu3)] (X = Cl, Br, I) have been prepared by reaction of the appropriate trihalide with SbnBu3 in n-hexane or CH2Cl2 solution, and characterized by microanal., IR, 1H, 13C{1H} and 71Ga NMR spectroscopy. X-ray crystal structures are reported for [InX3(SbnBu3)] (X = Cl, Br) and [GaX3(SbnBu3)]. Similar pseudo-tetrahedral complexes of AsEt3, [GaCl3(AsEt3)], [InCl3(AsEt3)] and the five-coordinate [InCl3(AsEt3)2] were also obtained and their structures determined Attempts to use [InCl3(SbR3)] and [GaCl3(SbR3)] (R = nBu, Et) as single source precursors for low pressure CVD growth of InSb or GaSb films were unsuccessful, instead producing elemental antimony, while [GaCl3(AsEt3)] and [InCl3(AsEt3)] failed to produce any deposition under similar conditions. In the part of experimental materials, we found many familiar compounds, such as Indium(III) bromide(cas: 13465-09-3Product Details of 13465-09-3)
Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Product Details of 13465-09-3
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary