Li, Ankun; Li, Yuxuan; Liu, Junjie; Chen, Jingqi; Lu, Kui; Qiu, Di; Fagnoni, Maurizio; Protti, Stefano; Zhao, Xia published the artcile< Metal-Free Trifluoromethylthiolation of Arylazo Sulfones>, Recommanded Product: (3-Bromophenyl)(trifluoromethyl)sulfane, the main research area is fluoromethylthiolation arylazo sulfone fluoromethyl arylsulfonothioate.
A visible-light-driven protocol for the synthesis of aryl trifluoromethyl thioethers under photocatalyst- and metal-free conditions has been pursued. The procedure exploits the peculiar properties of arylazo sulfones (having electron-rich or electron-poor substituents on the (hetero)aromatic ring) as photochem. precursors of aryl radicals and S-trifluoromethyl arylsulfonothioates as easy-to-handle trifluoromethylthiolating agents.
Journal of Organic Chemistry published new progress about Aromatic compounds, azo Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 2252-45-1 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3S, Recommanded Product: (3-Bromophenyl)(trifluoromethyl)sulfane.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary