Shi, Ji-Long; Hao, Huimin; Lang, Xianjun published the artcile< Phenol-TiO2 complex photocatalysis: visible light-driven selective oxidation of amines into imines in air>, Product Details of C7H8BrN, the main research area is phenol titania photocatalyst amine imine oxidation air.
Strong interfacial charge-transfer (ICT) has been observed between phenol and TiO2. It was demonstrated that a single Ph-O-Ti linkage could induce ICT transitions in the visible light region. By utilizing the surface complexation of phenol with TiO2, we, herein, present a new photocatalytic protocol for the selective oxidation of amines to imines in air. Our success depended on merging the phenol-TiO2 complex photocatalyst with (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO), so called cooperative photocatalysis, which improved stability of the surface-complexed phenol under the oxidative circumstance and promoted the selective conversion of amines. With 5 mol% of TEMPO as a co-catalyst and phenol-TiO2 complex (containing 0.8 mol% of phenol) as a photocatalyst, amines could be efficiently oxidized into imines with atm. O2 under blue light-emitting diode (LED) irradiation In addition, a mechanism is proposed to explain the visible-light photocatalytic performance of the present system.
Sustainable Energy & Fuels published new progress about Amines Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Product Details of C7H8BrN.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary