The author of 《Photoredox-catalyzed redox-neutral difluoroalkylation to construct perfluoroketones with difluoroenoxysilanes》 were Zou, Jian-Yu; Wang, Yu-Zhao; Sun, Wen-Hui; Lin, Wu-Jie; Liu, Xue-Yuan. And the article was published in Organic & Biomolecular Chemistry in 2021. Product Details of 401-55-8 The author mentioned the following in the article:
A mild and facile approach to construct various perfluoroketones via photo-catalyzed difluoroalkylation of difluoroenoxysilanes is developed. The reaction includes a strategy of combination of two fluorine-containing functional groups, which confers the reaction with characteristics like high efficiency, mild conditions, and broad scope. A variety of fluoroalkyl halides including perfluoroalkyl iodides, bromo difluoro esters and amides can be employed as radical precursors. Control experiments indicate that a single-electron transfer pathway may be involved in the reaction. In the experiment, the researchers used many compounds, for example, Ethylbromofluoroacetate(cas: 401-55-8Product Details of 401-55-8)
Ethylbromofluoroacetate(cas: 401-55-8) is a member of organofluorine compounds. Organofluorine compounds, which have carbon-fluorine bonds, show unique features such as high thermal and chemical stability, high surface activity, no light-absorbing ability, high pharmacological effect, and so on. Owing to their specific characters, they are indispensable chemicals for industry and our daily lives.Product Details of 401-55-8
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary