Organic bromides such as alkyl bromides are used as fumigants in agriculture to control insects. 90-59-5, formula is C7H4Br2O2, Name is 3,5-Dibromo-2-hydroxybenzaldehyde. Ethylene bromide is one of the commercially important organic bromides which are the component of leaded gasoline. Recommanded Product: 3,5-Dibromo-2-hydroxybenzaldehyde.
Kaya, Yeliz;Ercag, Ayse;Serdaroglu, Goncagul;Kaya, Savas;Grillo, Igor Barden;Rocha, Gerd Bruno research published 《 Synthesis, spectroscopic characterization, DFT calculations and molecular docking studies of new unsymmetric bishydrazone derivatives》, the research content is summarized as follows. Three unsym. isatin bishydrazone compounds I [R1 = R2 = Cl; R1 = Br, R2 = Cl; R1 = R2 = Br] were synthesized by the condensation of 3,5-dichloro-salicylaldehyde, 3-bromo-5-chloro-salicylaldehyde and 3,5-dibromo-salicylaldehyde with isatin monohydrazone, resp. The synthesized compounds I were characterized by elemental anal., 1H-NMR, FT-IR, UV-Vis spectroscopy and mass spectrometry technique. For studied mols. I, chem. parameters like frontier orbital energies, energy gap, electronegativity, chem. potential, chem. hardness, softness, electrophilicity, nucleophilicity, electrodonating power, electroaccepting power, polarizability and dipole moment were calculated and discussed. Investigating the validity of well-known electronic structure principles like maximum hardness, min. polarizability and min. electrophilicity principles in the study, it was determined which compound is more stable compared to others. A software having PRIMorDIA name was developed to explore reactivity and electronic structure in large biomols. by some of the authors of this paper. Mol. docking studies for these synthesized mols. I were performed using PRIMorDIA software. Considering the intramol. interactions, NBO analyzes of three bishydrazone derivatives I were conducted to evaluate the chem. behavior.
90-59-5, 3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes.
3,5-Dibromosalicylaldehyde, also known as 3,5-Dibromosalicylaldehyde, is a useful research compound. Its molecular formula is C7H4Br2O2 and its molecular weight is 279.91 g/mol. The purity is usually 95%.
3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes. 3,5-Dibromosalicylaldehyde can be used in the synthesis of Schiff base and can be used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).
3,5-Dibromosalicylaldehyde is a copper complex that has been synthesized from 3,5-dibromosalicylaldehyde and copper chloride. FTIR spectroscopy revealed that the coordination geometry of the copper complex is octahedral with two nitrogen atoms in the equatorial plane. The presence of hydrogen bonding interactions was confirmed by homologous protein adsorption experiments. This chemical structure was determined using X-ray crystallography and fluorescence probe experiments. The copper complex showed high affinity for malonic acid, which is an ester hydrochloride. The molecular mechanism of this interaction is based on adsorption, which occurs through hydrogen bonding interactions and hydrophobic interactions. Structural analysis revealed that the polymeric matrix consists of a three-dimensional network of crosslinked chains, while FTIR analysis indicated a possible disulfide bond between two cysteine residues., Recommanded Product: 3,5-Dibromo-2-hydroxybenzaldehyde
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary