Organic bromides such as alkyl bromides are used as fumigants in agriculture to control insects. 5445-17-0, formula is C4H7BrO2, Name is Methyl 2-bromopropanoate. Ethylene bromide is one of the commercially important organic bromides which are the component of leaded gasoline. Safety of Methyl 2-bromopropanoate.
Pavan, Paola;Lorandi, Francesca;De Bon, Francesco;Gennaro, Armando;Isse, Abdirisak A. research published 《 Enhancement of the Rate of Atom Transfer Radical Polymerization in Organic Solvents by Addition of Water: An Electrochemical Study.》, the research content is summarized as follows. Addition of water to organic solvents enhances the rate of atom transfer radical polymerization (ATRP). To understand the origin of this rate enhancement, the effects of H2O on the redox properties of [CuIITPMA]2+ and [BrCuIITPMA]+ (TPMA=tris(2-pyridylmethyl)amine), and on the ATRP equilibrium (KATRP) and activation rate (kact) constants of Me 2-bromopropionate by [CuITPMA]+ were investigated in CH3CN, DMF and DMSO and their mixtures with Me acrylate (MA). E°s of the complexes allowed evaluation of the relative halidophilicities of [CuIITPMA]2+ and [CuITPMA]+, KIIBr and KIBr, resp. KIIBr/KIBr dropped in pure solvents and solvent/MA mixtures when 11% (volume/volume) H2O was added, suggesting that H2O hampers the stability of the deactivator [BrCuIITPMA]+. Conversely, both kact and KATRP were enhanced by the presence of water. In solvent/MA mixtures (50/50, volume/volume), addition of 11% (volume/volume) H2O increased KATRP by a factor of 2-3, which could explain the accelerating effect of H2O on ATRP in organic solvents.
5445-17-0, Methyl 2-bromopropionate, also known as Methyl 2-bromopropionate, is a useful research compound. Its molecular formula is C4H7BrO2 and its molecular weight is 167 g/mol. The purity is usually 95%.
Methyl 2-bromopropionate is used in the synthesis of poly(ADP-Ribose)polymerase inhibitors derived from benzoxazin-3-one. Also used in the synthesis of 5-HT2C antagonists affecting serotonin levels.
Methyl 2-bromopropanoate is a chemical compound that can be synthesized in an asymmetric manner. The reaction of methyl 2-bromopropanoate with hydrochloric acid gives the corresponding carboxylic acid, methyl propanoate, and hydrogen bromide in a 1:1 ratio. It has been shown that methyl 2-bromopropanoate is a potential catalyst for the reduction of chloride to chloride ion via the borohydride reduction method. Methyl 2-bromopropanoate has also been used as a model system for studying halides and copper complexes. Magnetic resonance spectroscopy studies have revealed that this chemical compound has a high redox potential and kinetic properties., Safety of Methyl 2-bromopropanoate
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary