Organic bromides such as alkyl bromides are used as fumigants in agriculture to control insects. 5445-17-0, formula is C4H7BrO2, Name is Methyl 2-bromopropanoate. Ethylene bromide is one of the commercially important organic bromides which are the component of leaded gasoline. Synthetic Route of 5445-17-0.
Shi, Yanlin;Mudugamuwa, Chanaka J.;Abeysinghe, Thidas N.;Alotaibi, Yasser S. M.;Monteiro, Michael J.;Chalker, Justin M.;Lutkenhaus, Jodie L.;Jia, Zhongfan research published 《 Ionic Effect on Electrochemical Behavior of Water-Soluble Radical Polyelectrolytes》, the research content is summarized as follows. Water-soluble redox-active polymers (RAPs) have emerged as attractive electroactive materials for aqueous redox flow batteries because these systems rely on readily available size-exclusion membranes rather than expensive ion-selective membranes. While incorporating ionic units is the most effective strategy for forming water-soluble redox polyelectrolytes, little is known about how charges dictate their electrochem. behavior. Here, we design a series of water-soluble TEMPO (2,2,6,6-tetramethylpiperidyl-1-oxy) radical polyelectrolytes with identical radical distribution but various ionic groups through a sequential postmodification method. Phys. and electrochem. characterizations show disparate diffusion coefficients (D) and charge transfer kinetics (k0) of these radical polyelectrolytes at various pH. Particularly, pH exerts a strong impact on k0 of the neg. charged polymer (i.e., with carboxylic acid groups). The bimol. reaction rate kex determined from redox-induced polymer films shows electrostatic interactions between charged segments can enhance the electron self-exchange reaction rate by ten folds. The results suggest that charge effects are of great importance when designing water-soluble redox polymers for electrochem. applications.
Synthetic Route of 5445-17-0, Methyl 2-bromopropionate, also known as Methyl 2-bromopropionate, is a useful research compound. Its molecular formula is C4H7BrO2 and its molecular weight is 167 g/mol. The purity is usually 95%.
Methyl 2-bromopropionate is used in the synthesis of poly(ADP-Ribose)polymerase inhibitors derived from benzoxazin-3-one. Also used in the synthesis of 5-HT2C antagonists affecting serotonin levels.
Methyl 2-bromopropanoate is a chemical compound that can be synthesized in an asymmetric manner. The reaction of methyl 2-bromopropanoate with hydrochloric acid gives the corresponding carboxylic acid, methyl propanoate, and hydrogen bromide in a 1:1 ratio. It has been shown that methyl 2-bromopropanoate is a potential catalyst for the reduction of chloride to chloride ion via the borohydride reduction method. Methyl 2-bromopropanoate has also been used as a model system for studying halides and copper complexes. Magnetic resonance spectroscopy studies have revealed that this chemical compound has a high redox potential and kinetic properties., 5445-17-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary