Vinyl bromides undergo the Heck reaction, which involves C-C coupling with alkene to give substituted alkenes. 5445-17-0, formula is C4H7BrO2, Name is Methyl 2-bromopropanoate. Methyl bromide is a precursor in the manufacture of several chemicals and is employed as a soil sterilant, mainly for seed production. Electric Literature of 5445-17-0.
Watabe, Takuma;Aoki, Daisuke;Otsuka, Hideyuki research published 《 Enhancement of Mechanophore Activation in Mechanochromic Dendrimers by Functionalization of Their Surface》, the research content is summarized as follows. The mechanochem. reactions of a series of dendrimers with a mechanochromic core were systematically investigated, and drastic enhancement of their reactivity was observed after their surface functionalization. We recently reported the quant. and qual. mechano-responsive behavior characteristic of a radical-type mechanophore for mechanochromic dendrimers (MDs) with defined structures in the bulk. In the present study, we systematically investigated the mechanochem. response of a series of dendrimers with different functional groups on their surfaces by mech. grinding in the bulk. Effective activation of the mechanochromic core was achieved in higher-generation MDs with hydrogen-bonding amide groups on their surfaces. A comparison of the degree of activation of the MDs with that of linear analogs revealed that the chain overlap, mol. size, and polarity affect the efficiency of the transmission of the grinding force to the mechanochromic core.
Electric Literature of 5445-17-0, Methyl 2-bromopropionate, also known as Methyl 2-bromopropionate, is a useful research compound. Its molecular formula is C4H7BrO2 and its molecular weight is 167 g/mol. The purity is usually 95%.
Methyl 2-bromopropionate is used in the synthesis of poly(ADP-Ribose)polymerase inhibitors derived from benzoxazin-3-one. Also used in the synthesis of 5-HT2C antagonists affecting serotonin levels.
Methyl 2-bromopropanoate is a chemical compound that can be synthesized in an asymmetric manner. The reaction of methyl 2-bromopropanoate with hydrochloric acid gives the corresponding carboxylic acid, methyl propanoate, and hydrogen bromide in a 1:1 ratio. It has been shown that methyl 2-bromopropanoate is a potential catalyst for the reduction of chloride to chloride ion via the borohydride reduction method. Methyl 2-bromopropanoate has also been used as a model system for studying halides and copper complexes. Magnetic resonance spectroscopy studies have revealed that this chemical compound has a high redox potential and kinetic properties., 5445-17-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary