One prominent application of synthetic organobromine compounds is the use of polybrominated diphenyl ethers as fire-retardants, and in fact fire-retardant manufacture is currently the major industrial use of the element bromine. 5445-17-0, formula is C4H7BrO2, Name is Methyl 2-bromopropanoate, Electric Literature of 5445-17-0
Yamamoto, Takumi;Kato, Sota;Aoki, Daisuke;Otsuka, Hideyuki research published 《 A Diarylacetonitrile as a Molecular Probe for the Detection of Polymeric Mechanoradicals in the Bulk State through a Radical Chain-Transfer Mechanism》, the research content is summarized as follows. Since the beginning of polymer science, understanding the influence of mech. stress on polymer chains has been a fundamental and important research topic. The detection of mechanoradicals generated by homolytic cleavage of the polymer chains in solution has been studied in many cases. However, the detection of mechanoradicals in the bulk is still limited owing to their high reactivity. Herein, we propose an innovative strategy to detect mechanoradicals visually and quant. using a chain-transfer agent that generates relatively stable fluorescent radicals as a mol. probe. Mechanoradicals generated by ball milling of polystyrene samples were successfully detected by using a diarylacetonitrile compound as a fluorescent mol. probe through this radical chain-transfer mechanism. This probe enables the visualization and quant. evaluation of mechanoradicals generated by polymer-chain scission.
Electric Literature of 5445-17-0, Methyl 2-bromopropionate, also known as Methyl 2-bromopropionate, is a useful research compound. Its molecular formula is C4H7BrO2 and its molecular weight is 167 g/mol. The purity is usually 95%.
Methyl 2-bromopropionate is used in the synthesis of poly(ADP-Ribose)polymerase inhibitors derived from benzoxazin-3-one. Also used in the synthesis of 5-HT2C antagonists affecting serotonin levels.
Methyl 2-bromopropanoate is a chemical compound that can be synthesized in an asymmetric manner. The reaction of methyl 2-bromopropanoate with hydrochloric acid gives the corresponding carboxylic acid, methyl propanoate, and hydrogen bromide in a 1:1 ratio. It has been shown that methyl 2-bromopropanoate is a potential catalyst for the reduction of chloride to chloride ion via the borohydride reduction method. Methyl 2-bromopropanoate has also been used as a model system for studying halides and copper complexes. Magnetic resonance spectroscopy studies have revealed that this chemical compound has a high redox potential and kinetic properties., 5445-17-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary