On May 7, 2021, Zhou, Shaofang; Lv, Kang; Fu, Rui; Zhu, Changlei; Bao, Xiaoguang published an article.Synthetic Route of 2567-29-5 The title of the article was Nickel/Photoredox Dual Catalytic Cross-Coupling of Alkyl and Amidyl Radicals to Construct C(sp3)-N Bonds. And the article contained the following:
The construction of C(sp3)-N bonds via direct radical-radical cross-coupling under benign conditions is a desirable but challenging approach. Herein, the cross-coupling of alkyl and amidyl radicals to build aliphatic C-N bonds in a concise, mild, and oxidant-free manner is implemented by nickel/photoredox dual catalysis. In this protocol, the single electron transfer strategy is successfully employed to generate N- and C-centered radicals from sulfonyl azides/azidoformates and alkyltrifluoroborates, resp. The photocatalyst-induced triplet-triplet energy-transfer mechanism, however, might not be applicable to this reaction. The oxidative quenching pathway of the excited photocatalyst (RuII/*RuII/RuIII/RuII) combined with a possible NiI/NiII/NiIII/NiI catalytic cycle is proposed to account for the nickel/photoredox dual-catalyzed C(sp3)-N bond formation based on synergistic exptl. and computational studies. The experimental process involved the reaction of 4-(Bromomethyl)-1,1′-biphenyl(cas: 2567-29-5).Synthetic Route of 2567-29-5
The Article related to carbon nitrogen bond formation nickel photoredox dual catalysis, sulfonyl azide azidoformate alkyltrifluoroborate alkyl amidyl radical cross coupling, General Organic Chemistry: Synthetic Methods and other aspects.Synthetic Route of 2567-29-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary