Formula: C4H6BrFO2On May 6, 2022 ,《Synthesis of α-Fluorinated Areneacetates through Photoredox/Copper Dual Catalysis》 appeared in Organic Letters. The author of the article were Levitre, Guillaume; Granados, Albert; Cabrera-Afonso, Maria Jesus; Molander, Gary A.. The article conveys some information:
A metallaphotoredox method for the preparation of α-fluorinated areneacetates R-R1 [R = 4-MeC6H4, 3-FC6H4, 4-BrC6H4, etc.; R1 = CFC(O)OEt, CF2C(O)OEt, CF2P(O)OEt2] based on the synergistic combination of Ir/Cu dual catalysis from boronic acids was reported. The mild conditions allowed broad functional group tolerance, including substrates containing aldehydes, free phenols and N-Boc-protected amines. Mechanistic investigations support a process proceeding via photoredox/copper dual catalysis. The experimental part of the paper was very detailed, including the reaction process of Ethylbromofluoroacetate(cas: 401-55-8Formula: C4H6BrFO2)
Ethylbromofluoroacetate(cas: 401-55-8) is a member of organofluorine compounds. Organofluorine compounds, which have carbon-fluorine bonds, show unique features such as high thermal and chemical stability, high surface activity, no light-absorbing ability, high pharmacological effect, and so on. Owing to their specific characters, they are indispensable chemicals for industry and our daily lives.Formula: C4H6BrFO2
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary