Mazzarella, Daniele; Magagnano, Giandomenico; Schweitzer-Chaput, Bertrand; Melchiorre, Paolo published an article in ACS Catalysis. The title of the article was 《Photochemical Organocatalytic Borylation of Alkyl Chlorides, Bromides, and Sulfonates》.Recommanded Product: Ethylbromofluoroacetate The author mentioned the following in the article:
Reported herein is a photochem. strategy for the borylation of alkyl halides using bis(catecholato)diboron as the boron source. This method exploits the ability of a nucleophilic dithiocarbonyl anion organocatalyst to generate radicals via an SN2-based photochem. catalytic mechanism, which is not reliant on the redox properties of the substrates. Therefore, it grants access to alkyl boronic esters from readily available but difficult-to-reduce electrophiles, including benzylic and allylic chlorides, bromides, and mesylates, which were inert to or unsuitable for previously reported metal-free borylation protocols. In addition to this study using Ethylbromofluoroacetate, there are many other studies that have used Ethylbromofluoroacetate(cas: 401-55-8Recommanded Product: Ethylbromofluoroacetate) was used in this study.
Ethylbromofluoroacetate(cas: 401-55-8) is a member of organofluorine compounds. Organofluorine compounds, which have carbon-fluorine bonds, show unique features such as high thermal and chemical stability, high surface activity, no light-absorbing ability, high pharmacological effect, and so on. Owing to their specific characters, they are indispensable chemicals for industry and our daily lives.Recommanded Product: Ethylbromofluoroacetate
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary