Safety of EthylbromofluoroacetateOn May 1, 2020 ,《Photocatalytic Remote Oxyfluoroalkylation of Heteroalkynes: Regio-, Stereo-, and Site-Selective Access to Complex Fluoroalkylated (Z)-Alkenes》 appeared in Organic Letters. The author of the article were Shang, Tianbo; Zhang, Junhua; Zhang, Yan; Zhang, Fang; Li, Xin-Sheng; Zhu, Gangguo. The article conveys some information:
A visible-light-induced remote oxyfluoroalkylation, including ketofluoroalkylation and hydroxytrifluoromethylation, of heteroalkynes is developed with DMSO (DMSO) and H2O as the oxygen source, resp. It provides a facile access to complex fluoroalkylated (Z)-alkenes in satisfactory yields with excellent regio-, stereo-, and site-selectivity. The reaction involves an uncommon vinyl radical-induced intermol. C(sp3)-H functionalization, thus offering a good platform for the development of remote difunctionalization of alkynes. The results came from multiple reactions, including the reaction of Ethylbromofluoroacetate(cas: 401-55-8Safety of Ethylbromofluoroacetate)
Ethylbromofluoroacetate(cas: 401-55-8) is a member of organofluorine compounds. Organofluorine compounds, which have carbon-fluorine bonds, show unique features such as high thermal and chemical stability, high surface activity, no light-absorbing ability, high pharmacological effect, and so on. Owing to their specific characters, they are indispensable chemicals for industry and our daily lives.Safety of Ethylbromofluoroacetate
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary