Li, Shuo’s team published research in Organic Letters in 2020-02-21 | CAS: 452-63-1

Organic Letters published new progress about Azocines Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 452-63-1 belongs to class bromides-buliding-blocks, name is 1-Bromo-4-fluoro-2-methylbenzene, and the molecular formula is C7H6BrF, COA of Formula: C7H6BrF.

Li, Shuo published the artcileCross-Coupling Strategy for the Synthesis of Diazocines, COA of Formula: C7H6BrF, the main research area is diazocine preparation diastereoselective; bibenzyl preparation cascade coupling deprotection oxidation copper catalyst; bromobenzyl bromide reductive coupling.

Here, a new synthetic strategy was presented for the synthesis of diazocines I [R = H, 2,9-Cl2, 3,8-F2, etc.] starting from widely available 2-bromobenzyl bromides followed by insertion of a hydrazine unit via cascade C-N coupling reactions. The designated mols. were obtained in three simple steps.

Organic Letters published new progress about Azocines Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 452-63-1 belongs to class bromides-buliding-blocks, name is 1-Bromo-4-fluoro-2-methylbenzene, and the molecular formula is C7H6BrF, COA of Formula: C7H6BrF.

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary