Tron, Arnaud published the artcileReversible Photocapture of a [2]Rotaxane Harnessing a Barbiturate Template, COA of Formula: C12H23BrO2, the main research area is reversible photocapture rotaxane barbiturate template.
Photoirradiation of a hydrogen-bonded mol. complex comprising acyclic components, namely, a stoppered thread (1) with a central barbiturate motif and an optimized doubly anthracene-terminated acyclic Hamilton-like receptor (2b), leads to an interlocked architecture, which was isolated and fully characterized. The sole isolated interlocked photoproduct (Φ = 0.06) is a [2]rotaxane, with the dimerized anthracenes assuming a head-to-tail geometry, as evidenced by NMR spectroscopy and consistent with mol. simulation, physicochem., physicochem. (PM6). A different behavior was observed on irradiating homologous mol. complexes 1⊂2a, 1⊂2b, and 1⊂2c, where the spacers of 2a, 2b, and 2c incorporated 3, 6, and 9 methylene units, resp. While no evidence of interlocked structure formation was observed following irradiation of 1⊂2a, a kinetically labile rotaxane was obtained on irradiating the complex 1⊂2c, and ring slippage was revealed. A more stable [2]rotaxane was formed on irradiating 1⊂2b, whose capture is found to be fully reversible upon heating, thereby resetting the system, with some fatigue (38%) after four irradiation-thermal reversion cycles.
Journal of Organic Chemistry published new progress about [2+2] Photocycloaddition reaction. 55099-31-5 belongs to class bromides-buliding-blocks, name is Ethyl 10-bromodecanoate, and the molecular formula is C12H23BrO2, COA of Formula: C12H23BrO2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary