Rosso, Cristian published the artcileUnveiling the Synthetic Potential of Substituted Phenols as Fully Recyclable Organophotoredox Catalysts for the Iodosulfonylation of Olefins, Computed Properties of 111-83-1, the publication is ACS Catalysis (2022), 12(8), 4290-4295, database is CAplus.
An efficient photocatalytic procedure for the direct iodosulfonylation of terminal olefins RCHCH2 (R = Bu, cyclohexylmethyl, 4-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)butyl, etc.) with α-iodo phenylsulfones R1S(O)2CH(R2)I (R1 = Me, Ph, cyclohexyl, naphthalene-1-yl, etc.; R2 = H, Me) was described. Specifically, the process uses the simple, robust, and fully recyclable phenol derivative I as the precatalytic system and occurs with visible-light irradiation (450 nm). Mechanistic investigations proved the key role of the in situ generated photocatalyst, namely phenolate anion, which has shown high catalytic activity and considerable stability toward the operating conditions. Importantly, this photocatalytic transformation provides a wide variety of densely functionalized alkyl iodides RCH(I)CH2CH(R2)S(O)2R1 (23 examples, up to 95% yield). Finally, the synthetic potential of this photochem. transformation was demonstrated by scaling up the process under microfluidic conditions (up to 0.67 mmol h-1) while accessing a series of relevant product manipulations.
ACS Catalysis published new progress about 111-83-1. 111-83-1 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 1-Bromooctane, and the molecular formula is C8H17Br, Computed Properties of 111-83-1.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary