Saha, Subhadeep published the artcileCoordination cage-based emulsifiers: templated formation of metal oxide microcapsules monitored by in situ LC-TEM, Synthetic Route of 143-15-7, the publication is Chemistry – A European Journal (2022), 28(5), e202103406, database is CAplus and MEDLINE.
Metallo-supramol. self-assembly has yielded a plethora of discrete nanosystems, many of which show competence in capturing guests and catalyzing chem. reactions. However, the potential of low-mol. bottom-up self-assemblies in the development of structured inorganic materials has rarely been methodically explored so far. Herein, we present a new type of metallo-supramol. surfactant with the ability to stabilize non-aqueous emulsions for a significant period. The mol. design of the surfactant is based on a heteroleptic coordination cage (CGA-3; CGA=Cage-based Gemini Amphiphile), assembled from two pairs of organic building blocks, grouped around two Pd(II) cations. Shape-complementarity between the differently functionalized components generates discrete amphiphiles with a tailor-made polarity profile, able to stabilize non-aqueous emulsions, such as hexadecane-in-DMSO. These emulsions were used as a medium for the synthesis of spherical metal oxide microcapsules (titanium oxide, zirconium oxide, and niobium oxide) from soluble, water-sensitive alkoxide precursors by allowing a controlled dosage of water to the liquid-liquid phase boundary. Synthesized materials were analyzed by a combination of electron microscopic techniques. In situ liquid cell transmission electron microscopy (LC-TEM) was utilized for the first time to visualize the dynamics of the emulsion-templated formation of hollow inorganic titanium oxide and zirconium oxide microspheres.
Chemistry – A European Journal published new progress about 143-15-7. 143-15-7 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 1-Bromododecane, and the molecular formula is C12H25Br, Synthetic Route of 143-15-7.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary