Copolymerization of n-butyl acrylate with methyl methacrylate by a novel photoinitiator, 1-(bromoacetyl)pyrene was written by Mishra, Anuradha;Daswal, Swati. And the article was included in International Journal of Chemical Kinetics in 2007.Synthetic Route of C18H11BrO The following contents are mentioned in the article:
The photopolymerization efficiency of pyrene (Py), 1-acetylpyrene (AP), and 1-(bromoacetyl)pyrene (BP) for copolymerization of n-butylacrylate (BA) with methylmethacrylate (MMA) was compared. A kinetic study of solution copolymerization in DMSO at 30 ± 0.2° showed that the Py could not initiate copolymerization even after 20 h, whereas with AP as initiator, less than 1% conversion was observed However, introduction of a Br in α-Me group of AP significantly enhanced the percent conversion. The kinetics and mechanism of copolymerization of BA with MMA using BP as photoinitiator have been studied in detail. The system follows nonideal kinetics (Rp α |BP|0.67|BA|1|MMA|0.98), and degradative solvent transfer reasonably explains these kinetic nonidealities. The monomer reactivity ratios (MRRs) of MMA and BA have been estimated by the Finemann-Ross and Kelen-Tudos methods, by analyzing copolymer compositions determined by 1H-NMR spectra. The values of r1 (MMA) and r2 (BA) were found to be 2.17 and 0.44, resp., which suggested the high concentration of alternating sequences in the random copolymers obtained. This study involved multiple reactions and reactants, such as 2-Bromo-1-(pyren-1-yl)ethanone (cas: 80480-15-5Synthetic Route of C18H11BrO).
2-Bromo-1-(pyren-1-yl)ethanone (cas: 80480-15-5) belongs to organobromine compounds. Many of the organo bromine compounds are relatively nonpolar. Bromine is more electronegative than carbon (2.8 vs 2.5) and hence the carbon in a carbonbromine bond is electrophilic in nature. Commercially available organobromine pharmaceuticals include the vasodilator nicergoline, the sedative brotizolam, the anticancer agent pipobroman, and the antiseptic merbromin. Synthetic Route of C18H11BrO
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary