Chen, Bo published the artcileManganese(III)-Promoted Double Carbonylation of Anilines Toward α-Ketoamides Synthesis, Recommanded Product: 1-Bromooctane, the publication is Advanced Synthesis & Catalysis (2022), 364(3), 487-492, database is CAplus.
Employing anilines as nucleophiles in double carbonylation is a longstanding challenge. In this communication, a Mn(III)-promoted double carbonylation of alkylborates or Hantzsch esters with anilines toward the synthesis of α-ketoamides has been developed. By using easily available potassium alkyltrifluoroborates or Hantzsch esters as the starting material, and cheap and non-toxic Mn(OAc)3 · 2H2O as the promotor, a broad range of alkyl α-ketoamide derivatives were synthesized in moderate to good yields with excellent selectivity.
Advanced Synthesis & Catalysis published new progress about 111-83-1. 111-83-1 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 1-Bromooctane, and the molecular formula is C8H17Br, Recommanded Product: 1-Bromooctane.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary