Wu, Jicheng’s team published research in Organic Letters in 19 | CAS: 401-55-8

Organic Letters published new progress about 401-55-8. 401-55-8 belongs to bromides-buliding-blocks, auxiliary class Fluoride,Bromide,Aliphatic hydrocarbon chain,Ester, name is Ethylbromofluoroacetate, and the molecular formula is C6H8O3, Category: bromides-buliding-blocks.

Wu, Jicheng published the artcilePhotoredox-Catalyzed Cross-Coupling of Enamides for the Assembly of β-Difluoroimine Synthons, Category: bromides-buliding-blocks, the publication is Organic Letters (2017), 19(20), 5653-5656, database is CAplus and MEDLINE.

A photoredox-catalyzed formal Csp3-Csp3 cross-coupling reaction of enamides with bromodifluoro compounds is established. The resulting gem-difluoromethylenated γ-imines indicated high stability, excellent E/Z control, and broad functional group tolerance. These synthetic intermediates can efficiently transfer to difluoromethylenated γ-amino acids or δ-amino alcs. Mechanistic anal. indicates that a radical/SET mechanism proceeding via a difluoroalkyl radical may be involved in the catalytic cycle.

Organic Letters published new progress about 401-55-8. 401-55-8 belongs to bromides-buliding-blocks, auxiliary class Fluoride,Bromide,Aliphatic hydrocarbon chain,Ester, name is Ethylbromofluoroacetate, and the molecular formula is C6H8O3, Category: bromides-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary