Yin, Hongfei published the artcilePalladium Catalyzed Carbonylative Coupling of Alkyl Boron Reagents with Bromodifluoroacetamides, HPLC of Formula: 401-55-8, the publication is ACS Catalysis (2018), 8(5), 3853-3858, database is CAplus.
A catalytic protocol for the preparation of α,α-difluoro-β-alkyl-β-ketoamides is developed employing a Pd-mediated carbonylative Suzuki coupling between alkylboron reagents and bromodifluoroacetamides with COgen as the CO source. The reaction reveals good functional group tolerance providing a broad selection of α,α-difluoro-β-alkyl-β-ketoamides in moderate to good yields, which represent useful precursors for further synthetic manipulation. Finally, the methodol. is amenable to 13C-isotope labeling at the ketone carbon applying 13C-COgen.
ACS Catalysis published new progress about 401-55-8. 401-55-8 belongs to bromides-buliding-blocks, auxiliary class Fluoride,Bromide,Aliphatic hydrocarbon chain,Ester, name is Ethylbromofluoroacetate, and the molecular formula is C16H14O6, HPLC of Formula: 401-55-8.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary