Month: November 2022

On April 30, 2019, Wu, Pengfei; Zhu, Ruimin; Liu, Heyuan; Zhao, Baohua; Chen, Yanli; Li, Xiyou published an article.COA of Formula: C10H8BrNO2 The title of the article was Surface decorating of CH3NH3PbBr3 nanoparticles with chemically adsorbed porphyrin. And the article contained the following:

An organolead halide (CH3NH3PbBr3) nanoparticle was modified successfully with a porphyrin (POR) bearing an -NH3+ head group. The nanoparticles are homogeneous with high crystallinity. The photoluminescence of CH3NH3PbBr3 is quenched completely by the chem. adsorbed POR mols. The efficient energy transfer from CH3NH3PbBr3 to POR is responsible for the fluorescence quenching. The modified nanoparticles can be dispersed in organic solvents and the resulting dispersion remains stable for several days. This result provides a new way to tune the photophys. properties of organolead halide CH3NH3PbBr3 nanoparticles. [Figure not available: see fulltext.]. The experimental process involved the reaction of 2-(2-Bromoethyl)isoindoline-1,3-dione(cas: 574-98-1).COA of Formula: C10H8BrNO2

The Article related to carbon hydrogen nitrogen lead bromide porphyrin surface decoration, Surface Chemistry and Colloids: Other and other aspects.COA of Formula: C10H8BrNO2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On April 9, 2015, Matsuzaki, Yuichi; Kurahashi, Makoto published a patent.SDS of cas: 1261475-16-4 The title of the patent was Plant disease control composition containing tetrazolinone compound and QoI compound, and and use thereof. And the patent contained the following:

This plant disease control composition is effective in controlling plant diseases, and contains a tetrazolinone compound represented in formula I (R1 = C1-3 alkyl, etc.; R2 = H, etc.; R3 = C1-3 alkyl, etc.; Z1 = C1-3 alkyl; Z2 = C1-2 alkoxy, etc.; Z3 = C1-3 alkyl, etc.) and a QoI compound, and ideally, the weight ratio between the tetrazolinone compound and the QoI compound is tetrazolinone compound/QoI compound = 0.1/1 to 10/1. For example, a composition containing 3 ppm 1-[3-methyl-2-[2-methyl-4-(5-chloro-1,4-dimethyl-1H-pyrazol-3-yl)-phenoxymethyl]-phenyl]-4-methyl-1,4-dihydrotetrazol-5-one and 1 ppm azoxystrobin showed high preventive effect to Septoria tritici. The experimental process involved the reaction of 1-Bromo-3-isocyanato-2-methyl-benzene(cas: 1261475-16-4).SDS of cas: 1261475-16-4

The Article related to plant disease control tetrazolinone pesticide azoxystrobin mixture, Agrochemical Bioregulators: Microbial and other aspects.SDS of cas: 1261475-16-4

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On April 9, 2015, Matsuzaki, Yuichi; Kurahashi, Makoto published a patent.Product Details of 1261475-16-4 The title of the patent was Plant disease control composition containing tetrazolinone compound and pesticide, and use thereof. And the patent contained the following:

This plant disease control composition is effective in controlling plant diseases, and contains a tetrazolinone compound represented in formula I (R1 = C1-3 alkyl, etc.; R2 = H, etc.; R3 = C1-3 alkyl, etc.; Z1 = C1-3 alkyl; Z2 = C1-2 alkoxy, etc.; Z3 = C1-3 alkyl, etc.) and a pesticide, and ideally, the weight ratio between the tetrazolinone compound and the pesticide is tetrazolinone compound/pesticide = 0.1/1 to 10/1. For example, a composition containing 3 ppm 1-[3-methyl-2-[2-methyl-4-(5-chloro-1,4-dimethyl-1H-pyrazol-3-yl)-phenoxymethyl]-phenyl]-4-methyl-1,4-dihydrotetrazol-5-one and 1 ppm prothioconazole showed high preventive effect to Septoria tritici. The experimental process involved the reaction of 1-Bromo-3-isocyanato-2-methyl-benzene(cas: 1261475-16-4).Product Details of 1261475-16-4

The Article related to plant disease control tetrazolinone pesticide prothioconazole mixture, Agrochemical Bioregulators: Microbial and other aspects.Product Details of 1261475-16-4

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On November 27, 2014, Matsuzaki, Yuichi published a patent.Recommanded Product: 1-Bromo-3-isocyanato-2-methyl-benzene The title of the patent was Plant disease-controlling compositions containing tetrazolinones and QoI compounds, and method for controlling plant diseases. And the patent contained the following:

Title compositions contain tetrazolinones I (n = 0-5; R1 = halo, C1-6 alkyl, C1-6 alkoxy, C1-6 alkylthio, NO2, cyano; R2 = C1-3 alkyl, C3-4 cycloalkyl, halo, C1-3 alkoxy, C1-2 alkylthio, C2-3 alkenyl, C2-3 alkynyl; wherein the alkyls in R1 and R2 may be halogenated; when n ≥2, then R1 may differ from each other) and ≥1 QoI compounds chosen from azoxystrobin, pyraclostrobin, picoxystrobin, trifloxystrobin, mandestrobin, fluoxastrobin, kresoxim-Me, dimoxystrobin, orysastrobin, metominostrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, triclopyricarb, fenaminstrobin, pyribencarb, famoxadone, and fenamidone. Thus, a mixture of 1-[2-[[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxymethyl]-3-chlorophenyl]-4-methyl-1,4-dihydrotetrazol-5-one (3 ppm) plus azoxystrobin (1 ppm) strongly inhibited the growth of Septoria tritici. The experimental process involved the reaction of 1-Bromo-3-isocyanato-2-methyl-benzene(cas: 1261475-16-4).Recommanded Product: 1-Bromo-3-isocyanato-2-methyl-benzene

The Article related to agrochem fungicide tetrazolinone qoi compound, azoxystrobin agrochem fungicide tetrazolinone, Agrochemical Bioregulators: Microbial and other aspects.Recommanded Product: 1-Bromo-3-isocyanato-2-methyl-benzene

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On January 15, 2015, Azuma, Shuhei; Arimori, Sadayuki; Hasegawa, Nao published a patent.Recommanded Product: 1-Bromo-3-isocyanato-2-methyl-benzene The title of the patent was Tetrazolinone compound, pest control agent containing the compound, and pest control method. And the patent contained the following:

A tetrazolinone compound represented by formula I [Q is a 6-membered aromatic heterocyclic group which may have one or more atoms or groups selected from group P1 (provided that a hetero atom that composes the heterocyclic group is a nitrogen atom, and the number of the nitrogen atom is 1, 2 or 3); R1, R2, R3 and R11 are each a C1-C6 alkyl group, etc., which may have one or more atoms or groups selected from group P2; R4 and R5 are each a hydrogen atom, etc.; R6 is a C1-C6 alkyl group, etc., which may have one or more halogen atoms; R7, R8 and R9 are each a hydrogen atom, etc.; and X is an oxygen atom or sulfur atom.] has good control efficacy on pests. Thus, application of a solution containing 1-[2-[2-methyl-4-(4-methylpyridin-2-yl)phenoxymethyl]phenyl]-4-methyl-1,4-dihydrotetrazol-5-one (preparation given) to rice seedlings significantly decreased lesion due to Magnaporthe grisea. The experimental process involved the reaction of 1-Bromo-3-isocyanato-2-methyl-benzene(cas: 1261475-16-4).Recommanded Product: 1-Bromo-3-isocyanato-2-methyl-benzene

The Article related to tetrazolinone compound preparation pest control agent, phenoxymethylphenyltetrazolinone preparation agrochem fungicide, Agrochemical Bioregulators: Microbial and other aspects.Recommanded Product: 1-Bromo-3-isocyanato-2-methyl-benzene

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Berglund, Richard A.; Kreilein, Matthew M. published an article in 2006, the title of the article was Ozone.COA of Formula: C10H4Br2O8 And the article contains the following content:

Synthesis, properties, handling and applications of ozone in ozonization of alkenes, alkynes, aromatic compounds, acetals and heterocyclic compounds were reviewed. The experimental process involved the reaction of 3,6-Dibromobenzene-1,2,4,5-tetracarboxylic acid(cas: 41819-13-0).COA of Formula: C10H4Br2O8

The Article related to review ozone oxidant alkene alkyne ozonization safety, Inorganic Chemicals and Reactions: Reviews and other aspects.COA of Formula: C10H4Br2O8

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On March 4, 2020, Liu, Bin; Pappas, Charalampos G.; Ottele, Jim; Schaeffer, Gael; Jurissek, Christoph; Pieters, Priscilla F.; Altay, Meniz; Maric, Ivana; Stuart, Marc C. A.; Otto, Sijbren published an article.HPLC of Formula: 574-98-1 The title of the article was Spontaneous Emergence of Self-Replicating Molecules Containing Nucleobases and Amino Acids. And the article contained the following:

The conditions that led to the formation of the first organisms and the ways that life originates from a lifeless chem. soup are poorly understood. The recent hypothesis of “RNA-peptide coevolution” suggests that the current close relationship between amino acids and nucleobases may well have extended to the origin of life. We now show how the interplay between these compound classes can give rise to new self-replicating mols. using a dynamic combinatorial approach. We report two strategies for the fabrication of chimeric amino acid/nucleobase self-replicating macrocycles capable of exponential growth. The first one relies on mixing nucleobase- and peptide-based building blocks, where the ligation of these two gives rise to highly specific chimeric ring structures. The second one starts from peptide nucleic acid (PNA) building blocks in which nucleobases are already linked to amino acids from the start. While previously reported nucleic acid-based self-replicating systems rely on presynthesis of (short) oligonucleotide sequences, self-replication in the present systems start from units containing only a single nucleobase. Self-replication is accompanied by self-assembly, spontaneously giving rise to an ordered one-dimensional arrangement of nucleobase nanostructures. The experimental process involved the reaction of 2-(2-Bromoethyl)isoindoline-1,3-dione(cas: 574-98-1).HPLC of Formula: 574-98-1

The Article related to nucleobase amino acid self replication, Placeholder for records without volume info and other aspects.HPLC of Formula: 574-98-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On August 23, 2021, Xu, Donghan; Zhang, Cuijuan; Zhen, Yihan; Li, Yongdan published an article.Computed Properties of 574-98-1 The title of the article was Ferrocene/Phthalimide Ionic Bipolar Redox-Active Molecule for Symmetric Nonaqueous Redox Flow Batteries. And the article contained the following:

Sym. nonaqueous redox flow batteries (NARFBs) that utilize bipolar redox-active organic mols. (BROMs) provide a facile strategy to mitigate the crossover issue. However, their performance has lagged behind due to the low solubility of organic redox species and poor high-current operations. To address these tech. hurdles, a series of ionic BROMs based on ferrocene (Fc) and phthalimide (Ph) moieties with fast mass and charge-transfer kinetic are synthesized, which show high solubility and ionic conductivity Both computational and exptl. results show that the extended chain length between phthalimide moiety and quaternary nitrogen atom and the acidity of the solvent play a pivotal part in determining the stability of active materials and thus the cycling stability of NARFB. The assembled sym. NARFB shows an open-circuit voltage of 2.04 V, cycling capacity retention of 99.8% per cycle, and energy efficiency of 77.0% over 50 cycles at 20 mA cm-2. Furthermore, the battery yields a peak power d. of 110 mW cm-2 at 90 mA cm-2, which outperforms most NARFBs. This work demonstrates a promising mol. engineering strategy to improve the cycling stability of BROMs and to enable the high-current operation of sym. NARFB. The experimental process involved the reaction of 2-(2-Bromoethyl)isoindoline-1,3-dione(cas: 574-98-1).Computed Properties of 574-98-1

The Article related to ferrocene phthalimide redox flow battery, Placeholder for records without volume info and other aspects.Computed Properties of 574-98-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On February 5, 2021, Quiroga-Campano, Cinthia; Gomez-Machuca, Horacio; Moris, Silvana; Pessoa-Mahana, Hernan; Jullian, Carolina; Saitz, Claudio published an article.Product Details of 574-98-1 The title of the article was Synthesis of calix[4]arenes bearing thiosemicarbazone moieties with naphthalene groups: Highly selective turn off/on fluorescent sensor for Cu(II) recognition.. And the article contained the following:

Calix[4]arenes-based fluorescent chemosensors containing thiosemicarbazone as a binding site and naphthalene as a fluorogenic unit in a 1,3-alternate (L1) and cone (L2) conformation, were synthesized and examined for their binding abilities towards anions and cations using different spectroscopic techniques. Both receptors L1 and L2, exhibited an off/on fluorescence behavior due to complex formation with Cu(II). They showed selective recognition of Cu(II) in presence of other cations and anions detecting up to 4.25 μg/L for L1 and 1.58 μg/L for L2, both in acetonitrile. The complexation behavior was studied by 1H NMR and FT-IR spectral anal., indicating that copper interacts with sulfur and with imine nitrogen of the thiosemicarbazone. No major differences in the selectivity and sensitivity were found between calix[4]arene receptors in 1,3-alternate and cone conformation. The 1H NMR spectra indicates that receptor L2 changed its conformation from cone to pinched cone, stiffening the conformation due to interaction of the thiosemicarbazone moiety with copper. The experimental process involved the reaction of 2-(2-Bromoethyl)isoindoline-1,3-dione(cas: 574-98-1).Product Details of 574-98-1

The Article related to calixarene fluorescent indicator copper ion, Placeholder for records without volume info and other aspects.Product Details of 574-98-1

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

On October 11, 2018, Sharma, Amit; Lee, Min-Goo; Shi, Hu; Won, Miae; Arambula, Jonathan F.; Sessler, Jonathan L.; Lee, Jin Yong; Chi, Sung-Gil; Kim, Jong Seung published an article.Application In Synthesis of (6-Bromohexyl)triphenylphosphonium bromide The title of the article was Overcoming Drug Resistance by Targeting Cancer Bioenergetics with an Activatable Prodrug. And the article contained the following:

Nearly without exception, all known cancer chemotherapeutics elicit a resistance response over time. The resulting resistance is correlated with poor clin. outcomes. Here, we report an approach to overcoming resistance through reprogramming oncogene-directed alterations in mitochondrial metabolism before drug activation while simultaneously circumventing drug efflux pumps. Conjugate C1 increases cancer cell apoptosis and inhibits regrowth of drug-resistant tumors, as inferred from efficacy studies carried out in human cancer cells and in Dox-resistant xenograft tumor models. It also displays minimal whole-animal toxicity. These benefits are ascribed to an ability to evade chemoresistance by switching cancer cell metabolism back to normal mitochondrial oxidative phosphorylation while helping target the active Dox to first the mitochondrion and then the nucleus. The experimental process involved the reaction of (6-Bromohexyl)triphenylphosphonium bromide(cas: 83152-22-1).Application In Synthesis of (6-Bromohexyl)triphenylphosphonium bromide

The Article related to cancer doxorubicin drug resistance bioenergetics, Placeholder for records without volume info and other aspects.Application In Synthesis of (6-Bromohexyl)triphenylphosphonium bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary