Dower, William V.’s team published research in Tetrahedron in 42 | CAS: 69361-41-7

Tetrahedron published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, Product Details of C7H13BrSi.

Dower, William V. published the artcileThermal conversion of 1,5,9-triynes. [2 + 2 + 2] Cycloadditions or [3.3]sigmatropic shifts?, Product Details of C7H13BrSi, the publication is Tetrahedron (1986), 42(6), 1873-81, database is CAplus.

The gas phase pyrolysis products [labeled and unlabeled naphthalene and [1,2:4,5]dicyclobutabenzene or hexaradialene] of RCC(CH2)2CC(CH2)2CCR [R = H, D (I)] and HCC(CH2)213C13C(CH2)2CCH (II) or 1,5,9-cyclododecatriyne (III) and III–1,10–13C2 (IV), examined at 400-600°/10-4-40 tor with ∼1 ms-15 s contact times, show that the mechanism involves a series of [3.3] sigmatropic shifts; [2 + 2 + 3] cycloadditions of the alkyne units do not occur. The preparation of I, II, III, and IV are discussed.

Tetrahedron published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, Product Details of C7H13BrSi.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary