Gu, Yiting published the artcileDefunctionalization of sp3 C-Heteroatom and sp3 C-C Bonds Enabled by Photoexcited Triplet Ketone Catalysts, Recommanded Product: 1-Bromododecane, the publication is ACS Catalysis (2022), 12(2), 1031-1036, database is CAplus.
A general strategy for enabling a light-induced defunctionalization of sp3 C-heteroatom and sp3 C-C bonds with triplet ketone catalysts and bipyridine additives was disclosed. This protocol was characterized by its broad scope without recourse to transition metal catalysts or stoichiometric exogeneous reductants, thus offering a complementary technique for activating σ sp3 C-C(heteroatom) bonds. Preliminary mechanistic studies suggest that the presence of 2,2′-bipyridines improves the lifetime of ketyl radical intermediates.
ACS Catalysis published new progress about 143-15-7. 143-15-7 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 1-Bromododecane, and the molecular formula is C12H25Br, Recommanded Product: 1-Bromododecane.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary