Reduction of sulfur with borohydride exchange resin in methanol: application to rapid and selective synthesis of disulfides was written by Bandgar, B. P.;Uppalla, L. S.;Sadavarte, V. S.. And the article was included in Tetrahedron Letters in 2001.Safety of 1-Bromo-6-methoxyhexane This article mentions the following:
A convenient and rapid method for the synthesis of sym. disulfides from alkyl or aryl alkyl halides using sulfurated borohydride exchange resin under anhydrous conditions is described. Selective transfer of sulfur to an alkyl group rather than an aryl group is achieved using this methodol. The anion exchange resin-bound borohydride was prepared as reported previously, by stirring sodium borohydride with Tulsion A-27 (anion exchange resin). In the experiment, the researchers used many compounds, for example, 1-Bromo-6-methoxyhexane (cas: 50592-87-5Safety of 1-Bromo-6-methoxyhexane).
1-Bromo-6-methoxyhexane (cas: 50592-87-5) belongs to organobromine compounds. Most of the natural organobromine compounds are produced by marine organisms, and several brominated metabolites with antibacterial, antitumor, antiviral, and antifungal activity have been isolated from seaweed, sponges, corals, molluscs, and others. Bromine-containing agents predominate because not only are they more efficient than similar chlorine-containing species, but also the high atomic weight of bromine ensures that it is present in a high mass fraction within most organobromine compounds.Safety of 1-Bromo-6-methoxyhexane
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary