Beletskaya, I. P. et al. published their research in Zhurnal Obshchei Khimii in 1964 | CAS: 2178-24-7

Ethyl (2-bromophenyl)acetate (cas: 2178-24-7) belongs to organobromine compounds. Most of the natural organobromine compounds are produced by marine organisms, and several brominated metabolites with antibacterial, antitumor, antiviral, and antifungal activity have been isolated from seaweed, sponges, corals, molluscs, and others. Bromine-containing agents predominate because not only are they more efficient than similar chlorine-containing species, but also the high atomic weight of bromine ensures that it is present in a high mass fraction within most organobromine compounds.Recommanded Product: 2178-24-7

Synthesis of some organomercury salts of the type XC6H4CH(HgBr)CO2Et was written by Beletskaya, I. P.;Artamkina, G. A.;Shevlyagina, E. A.;Reutov, O. A.. And the article was included in Zhurnal Obshchei Khimii in 1964.Recommanded Product: 2178-24-7 This article mentions the following:

O-BrC6H4CH2CN refluxed in EtOH-concentrated H2SO4 5 h. gave 77% o-BrC6H4CH2CO2Et (I), b7 128°, m. 34.5°. Similarly was prepared the m-isomer, 75%, b2 120-1°, n20D 1.5348, d20 1.3810. p-EtC6H4CH2CO2Et, b4 110°, 1.4970, 1.013, was prepared in 82% yield from the acid and EtOH. I in CCl4 was brominated under an incandescent lamp and gave XC6H4CHBrCO2Et (II) (X = o-Br), 50%, b1 107°, 1.5781, 1.7266. Similarly was prepared the m-isomer, 60%, b3 148-9°, 1.5712, 1.7010, and II (X = p-O2N), 55%, b4 165°, 1.5580, -. Et p-ethylmandelate and PBr3 in CHCl3 at first with cooling, then 0.5 h. on a steam bath, gave 73% p-EtC6H4CHBrCO2Et, b4 125°, 1.5350, 1.3227. Similarly were prepared 60% p-iso-Pr analog, b6 142°, 1.5260, 1.2800, and p-methoxy analog, 65%, b3 150°, 1.5500, 1.4050. Shaking II with Hg gave 51% p-MeC6H4CH(HgBr)CO2Et (III), m. 70°, 50% o-bromo analog, m. 91°, 40% m-bromo analog, m. 69°, 70% p-Et analog, m. 74°, 68% p-nitro analog, m. 135°, and 89% p-iso-Pr analog, m. 95°. In case the product precipitated as an oil, indicating the formation of R2Hg, the mixture was treated with HgBr2 to effect conversion to RHgBr. If the preparation of III was run at 50-60°, the product was 60% (p-MeC6H4CHCO2Et)2, m. 151°. Similarly was obtained the p-ethylphenyl analog, 15%, m. 125°. The reaction of the p-anisyl member with Hg gave only a tar that was free of Hg. A previously reported substance (loc. cit.), m. 145°, was shown to be BrHgCH2C6H4CH2CO2Et, rather than III. In the experiment, the researchers used many compounds, for example, Ethyl (2-bromophenyl)acetate (cas: 2178-24-7Recommanded Product: 2178-24-7).

Ethyl (2-bromophenyl)acetate (cas: 2178-24-7) belongs to organobromine compounds. Most of the natural organobromine compounds are produced by marine organisms, and several brominated metabolites with antibacterial, antitumor, antiviral, and antifungal activity have been isolated from seaweed, sponges, corals, molluscs, and others. Bromine-containing agents predominate because not only are they more efficient than similar chlorine-containing species, but also the high atomic weight of bromine ensures that it is present in a high mass fraction within most organobromine compounds.Recommanded Product: 2178-24-7

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary