Investigation of the Adsorption of Gaseous Aromatic Compounds at Surfaces Coated with Heptakis(6-thio-6-deoxy)-β-cyclodextrin by Surface-Enhanced Raman Scattering was written by Hill, Wieland;Fallourd, Valerie;Klockow, Dieter. And the article was included in Journal of Physical Chemistry B in 1999.Application of 53784-83-1 This article mentions the following:
Heptakis(6-thio-6-deoxy)-β-cyclodextrin (TCD) was prepared and chemisorbed at the surface of rough silver substrates for surface-enhanced Raman scattering (SERS). The enhanced adsorption of methyl orange and the stability of its azo form at the TCD-coated substrates proved the capability of the immobilized TCD to form inclusion complexes with organic guest mols. This complexation was used for the detection of aromatics in the gas phase. Toluene, ethylbenzene, m-xylene, chlorobenzene, and m-dichlorobenzene were strongly adsorbed at the TCD-coated substrates, thus making possible the detection of low concentrations, as for example 15 ppm of m-dichlorobenzene. Benzene was weakly adsorbed and detectable in high concentrations only. Since the strongly adsorbed aromatics desorb very slowly, TCD-coated substrates may be applicable for the detection of slowly changing concentrations or as integrating sensors in the surveillance of chem. exposures. The capability of immobilized TCD to adsorb also polycyclic aromatic hydrocarbons was demonstrated using naphthalene. In the experiment, the researchers used many compounds, for example, Heptakis(6-Bromo-6-Deoxy)-β-Cyclodextrin (cas: 53784-83-1Application of 53784-83-1).
Heptakis(6-Bromo-6-Deoxy)-β-Cyclodextrin (cas: 53784-83-1) belongs to organobromine compounds. Most of the natural organobromine compounds are produced by marine organisms, and several brominated metabolites with antibacterial, antitumor, antiviral, and antifungal activity have been isolated from seaweed, sponges, corals, molluscs, and others. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Application of 53784-83-1
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary