Nickel-Catalyzed Asymmetric Negishi Cross-Coupling of Secondary Allylic Chlorides with Alkylzincs was written by Son, Sunghee;Fu, Gregory C.. And the article was included in Journal of the American Chemical Society in 2008.Product Details of 57293-19-3 This article mentions the following:
Complementing previous advances in allylation chem., an effective nickel/Pybox catalyst for regioselective asym. Negishi cross-couplings of racemic secondary allylic chlorides with readily available organozinc halides has been developed. The method has been applied in two key steps of a formal total synthesis of fluvirucinine A1. In the experiment, the researchers used many compounds, for example, 1-(3-Bromopropyl)-4-methoxybenzene (cas: 57293-19-3Product Details of 57293-19-3).
1-(3-Bromopropyl)-4-methoxybenzene (cas: 57293-19-3) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Product Details of 57293-19-3
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary