Synthesis of new pyrrole-pyridine-based ligands using an in situ Suzuki coupling method was written by Boettger, Matthias;Wiegmann, Bjoern;Schaumburg, Steffen;Jones, Peter G.;Kowalsky, Wolfgang;Johannes, Hans-Hermann. And the article was included in Beilstein Journal of Organic Chemistry in 2012.Related Products of 22426-14-8 This article mentions the following:
The compounds 6-(pyrrol-2-yl)-2,2′-bipyridine, 2-(pyrrol-2-yl)-1,10-phenanthroline and 2-(2-(N-methylbenz[d,e]imidazole))-6-(pyrrol-2-yl)pyridine were synthesized by using an in situ generated boronic acid for the Suzuki coupling. Crystals of the products could be grown and exhibited interesting structures by X-ray anal., one of them showing a chain-like network with the adjacent mols. linked to each other via intermol. N-H···N hydrogen bonds. In the experiment, the researchers used many compounds, for example, 2-Bromo-1,10-phenanthroline (cas: 22426-14-8Related Products of 22426-14-8).
2-Bromo-1,10-phenanthroline (cas: 22426-14-8) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.Related Products of 22426-14-8
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary