Treindl, L. et al. published their research in Canadian Journal of Chemistry in 1969 | CAS: 4457-67-4

1-Bromo-4-methoxybutane (cas: 4457-67-4) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.Recommanded Product: 1-Bromo-4-methoxybutane

Kinetic solvent isotope effect, solvent reorganization and the Sn1-Sn2 mechanism was written by Treindl, L.;Robertson, Ross Elmore;Sugamori, S. E.. And the article was included in Canadian Journal of Chemistry in 1969.Recommanded Product: 1-Bromo-4-methoxybutane This article mentions the following:

The temperature dependence of the rates of solvolysis were determined in D2O for tert-Bu chloride, 2,2-dibromopropane, 2-bromo-2-chloropropane, and 2-chloro-2-methylpropyl Me ether, and corresponding values of ΔHîŒ? ΔSîŒ? and ΔCp are derived. Values of ΔHîŒ?and ΔSîŒ?from the solvolysis of 7 other halides and 2 benzenesulfonates were estimated from rate determinations at 2 temperatures in D2O. A comparison of these values with terms from corresponding experiments in H2O provide values of δ1ΔGîŒ? δ1ΔHîŒ? and δ1ΔSîŒ?characterizing the kinetic solvent isotope effect. While δ1ΔGîŒ?appears to have about the same value for a wide range of halides of different structure irresp. of the probable mechanism of reaction, systematic differences in δ1ΔHîŒ?and δ1ΔSîŒ?differentiate those reacting by an SN2 mechanism from those reacting by an SN1 mechanism. This difference is in the direction suggesting a loosening of solvent structure in the activation process in agreement with indications obtained from the corresponding values of the heat capacity of activation. In the experiment, the researchers used many compounds, for example, 1-Bromo-4-methoxybutane (cas: 4457-67-4Recommanded Product: 1-Bromo-4-methoxybutane).

1-Bromo-4-methoxybutane (cas: 4457-67-4) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.Recommanded Product: 1-Bromo-4-methoxybutane

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary