Copper-catalyzed cross-coupling reaction between aryl(trialkyl)silanes and alkyl halides was written by Komiyama, Takeshi;Minami, Yasunori;Hiyama, Tamejiro. And the article was included in Chemistry Letters in 2018.Recommanded Product: 1-Bromo-4-methoxybutane This article mentions the following:
Simple aryl(trialkyl)silanes underwent cross-coupling reaction with alkyl (pseudo)halides in the presence of copper iodide/phenanthroline catalyst and cesium fluoride was reported. Various aryl(trialkyl)silanes and alkyl electrophiles having iodine, bromine, chlorine and tosyloxy group were applicable to the present reaction. Because such silanes were stable and readily accessible by catalytic C-H silylation, this protocol allowed the synthesis of alkylarenes rapidly. In the experiment, the researchers used many compounds, for example, 1-Bromo-4-methoxybutane (cas: 4457-67-4Recommanded Product: 1-Bromo-4-methoxybutane).
1-Bromo-4-methoxybutane (cas: 4457-67-4) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.Recommanded Product: 1-Bromo-4-methoxybutane
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary