Mononuclear Copper(II)-Superoxo Complexes that Mimic the Structure and Reactivity of the Active Centers of PHM and DβM was written by Kunishita, Atsushi;Kubo, Minoru;Sugimoto, Hideki;Ogura, Takashi;Sato, Kazunobu;Takui, Takeji;Itoh, Shinobu. And the article was included in Journal of the American Chemical Society in 2009.HPLC of Formula: 14425-64-0 This article mentions the following:
Mononuclear Cu(II)-superoxo complexes 2X-OOâ?/sup> (I) having triplet (S = 1) ground states were obtained via reaction of O2 with the Cu(I) starting materials 1X (II) supported by tridentate ligands LX [1-(2-p-X-phenethyl)-5-(2-pyridin-2-ylethyl)-1,5-diazacyclooctane; X = CH3, H, NO2] in various solvents. The superoxo complexes 2X-OOâ?/sup> (I) mimic the structure [tetrahedral geometry with an end-on (η1)-bound O2â?] and the aliphatic C-H bond activation chem. of peptidylglycine α-hydroxylating monooxygenase and dopamine β-monooxygenase. In the experiment, the researchers used many compounds, for example, 1-(2-Bromoethyl)-4-methoxybenzene (cas: 14425-64-0HPLC of Formula: 14425-64-0).
1-(2-Bromoethyl)-4-methoxybenzene (cas: 14425-64-0) belongs to organobromine compounds. Many of the organo bromine compounds are relatively nonpolar. Bromine is more electronegative than carbon (2.8 vs 2.5) and hence the carbon in a carbonbromine bond is electrophilic in nature. One prominent application of synthetic organobromine compounds is the use of polybrominated diphenyl ethers as fire-retardants, and in fact fire-retardant manufacture is currently the major industrial use of the element bromine.HPLC of Formula: 14425-64-0
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary