Forming Tertiary Organolithiums and Organocuprates from Nitrile Precursors and their Bimolecular Reactions with Carbon Electrophiles to Form Quaternary Carbon Stereocenters was written by Schnermann, Martin J.;Untiedt, Nicholas L.;Jimenez-Oses, Gonzalo;Houk, Kendall N.;Overman, Larry E.. And the article was included in Angewandte Chemie, International Edition in 2012.Product Details of 57293-19-3 This article mentions the following:
A general procedure for the synthesis of tertiary trialkyl-substituted organolithiums and organocuprates was reported. These intermediates was employed in the stereocontrolled construction of quaternary carbon stereocenters. In the experiment, the researchers used many compounds, for example, 1-(3-Bromopropyl)-4-methoxybenzene (cas: 57293-19-3Product Details of 57293-19-3).
1-(3-Bromopropyl)-4-methoxybenzene (cas: 57293-19-3) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. Commercially available organobromine pharmaceuticals include the vasodilator nicergoline, the sedative brotizolam, the anticancer agent pipobroman, and the antiseptic merbromin. Product Details of 57293-19-3
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary